Stereoretentive Chlorination of Cyclic Alcohols Catalyzed by Titanium(IV) Tetrachloride: Evidence for a Front Side Attack Mechanism
نویسندگان
چکیده
منابع مشابه
Iridium-Catalyzed 1,3-Hydrogen Shift/Chlorination of Allylic Alcohols**
Chlorinated compounds are among the most common and versatile building blocks in organic synthesis. Among these, achlorocarbonyl derivatives are of synthetic value owing to the variety of functional groups that can be introduced both at the chlorinated a-carbon atom and at the carbonyl functionality. For instance, they readily undergo substitution/addition reactions and cross-coupling reactions...
متن کاملDirect chlorination of alcohols with chlorodimethylsilane catalyzed by a gallium trichloride/tartrate system under neutral conditions.
The reaction of secondary alcohols 1 with chlorodimethylsilane (HSiMe(2)Cl) proceeded in the presence of a catalytic amount of GaCl(3)/diethyl tartrate to give the corresponding organic chlorides 3. In the catalytic cycle, the reaction of diethyl tartrate 4a with HSiMe(2)Cl 2 gives the chlorosilyl ether 5 with generation of H(2). Alcohol-exchange between the formed chlorosilyl ether 5 and the s...
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VANET (Vehicular Ad-hoc Network) which is a hy- brid network (combination of infrastructure and infra- structure-less networks) is an emergent technology with promising future as well as great challenges especially in security. By the other hand this type of network is very sensible to safety problem. This paper focuses on a new mechanism for DoS (denial of service) attacks on the physical and ...
متن کاملA Mechanism for Detecting and Identifying DoS attack in VANET
VANET (Vehicular Ad-hoc Network) which is a hy- brid network (combination of infrastructure and infra- structure-less networks) is an emergent technology with promising future as well as great challenges especially in security. By the other hand this type of network is very sensible to safety problem. This paper focuses on a new mechanism for DoS (denial of service) attacks on the physical and ...
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Horseradish peroxidase and chlorite, NaC102, are able to catalyze chlorination of monochlorodimedone to form dichlorodimedone. Catalytic amounts of horseradish peroxidase act to disproportionate chlorite forming chlorine dioxide and chloride ion. The chlorine dioxide thus formed is responsible for the chlorination of monochlorodimedone. It was previously thought (Chiang, R., Rand-Meir, T., Maki...
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ژورنال
عنوان ژورنال: The Journal of Organic Chemistry
سال: 2013
ISSN: 0022-3263,1520-6904
DOI: 10.1021/jo3023439